| Day | Date | Opponent | Location | Outcome/Time |
| Fri | 09/03/1999 | # 5 Long Beach State | Long Beach, Calif. (LBSU Tournament) | L, 3-1 Recap | Stats |
| Fri | 09/03/1999 | # 8USC | Long Beach, CA (LBSU Tournament) | L, 3-0 Recap | Stats |
| Sat | 09/04/1999 | # 14Illinois | Long Beach, CA (LBSU Tournament) | W, 3-2 Recap | Stats |
| Sat | 09/04/1999 | Massachusetts | Long Beach, Calif. (LBSU Tournament) | W, 3-2 Recap | Stats |
| Fri | 09/10/1999 | # 9 Florida | Madison, Wis. (Wisconsin Classic) | L, 3-1 Recap | Stats |
| Sat | 09/11/1999 | Dayton | Madison, Wis. (Wisconsin Classic) | W, 3-1 Recap | Stats |
| Tue | 09/14/1999 | East Carolina | Greenville, N.C. | W, 3-0 Recap | Stats |
| Fri | 09/17/1999 | American | Chapel Hill, N.C. (Carolina/Nike Classic) | W, 3-1 Recap | Stats |
| Sat | 09/18/1999 | Campbell | Chapel Hill, N.C. (Carolina/Nike Classic) | W, 3-0 Recap | Stats |
| Sat | 09/18/1999 | Providence | Chapel Hill, N.C. (Carolina/Nike Classic) | W, 3-0 Recap | Stats |
| Tue | 09/21/1999 | North Carolina-Charlotte | Charlotte, N.C. | W, 3-0 Recap | Stats |
| Fri | 09/24/1999 | Virginia* | Charlottesville, Va. | W, 3-0 Recap | Stats |
| Sat | 09/25/1999 | Maryland* | College Park, Md. | W, 3-0 Recap | Stats |
| Fri | 10/01/1999 | Duke* | Chapel Hill, N.C. | W, 3-0 Recap | Stats |
| Sat | 10/02/1999 | Wake Forest* | Chapel Hill, N.C. | W, 3-2 Recap | Stats |
| Tue | 10/05/1999 | Georgia Tech* | Atlanta, Ga. | W, 3-1 Recap | Stats |
| Sat | 10/09/1999 | # 13 Clemson* | Clemson, S.C. | W, 3-1 Recap | Stats |
| Tue | 10/12/1999 | North Carolina State* | Raleigh, N.C. | W, 3-2 Recap | Stats |
| Fri | 10/15/1999 | Florida State* | Tallahassee, FL | W, 3-0 Recap | Stats |
| Sat | 10/16/1999 | Jacksonville | Jacksonville, Fla. | W, 3-0 Recap | Stats |
| Fri | 10/22/1999 | # 14 Clemson* | Chapel Hill, N.C. | L, 3-2 Recap | Stats |
| Sat | 10/23/1999 | Georgia Tech* | Chapel Hill, N.C. | W, 3-1 Recap | Stats |
| Thu | 10/28/1999 | North Carolina State* | Chapel Hill, N.C. | W, 3-1 Recap | Stats |
| Tue | 11/02/1999 | Campbell | Chapel Hill, N.C. | W, 3-0 Recap | Stats |
| Fri | 11/05/1999 | Wake Forest* | Winston- Salem, NC | W, 3-2 Recap | Stats |
| Sun | 11/07/1999 | Duke* | Durham, N.C. | L, 3-2 Recap | Stats |
| Tue | 11/09/1999 | Maryland* | Chapel Hill, N.C. | W, 3-0 Recap | Stats |
| Fri | 11/12/1999 | Florida State* | Chapel Hill, N.C. | W, 3-0 Recap | Stats |
| Sat | 11/13/1999 | Virginia* | Chapel Hill, N.C. | W, 3-0 Recap | Stats |
| Fri | 11/19/1999 | NC State^ | Orlando, Fla. (ACC Championships) | W, 3-1 Recap | Stats | Quotes |
| Sat | 11/20/1999 | Wake Forest^ | Orlando, Fla. | W, 3-1 |
| Sun | 11/21/1999 | # 15 Clemson^ | Orlando, Fla. | W, 3-1 Recap | Stats |
| Thu | 12/02/1999 | Northern Arizona~ | College Station, Texas (First / Second Round) | W, 3-0 Recap |
| Fri | 12/03/1999 | Texas A&M~ | College Station, Texas (NCAA Second Round) | L, 3-0 Recap | Quotes |